You mention the 200L, which is ungodly expensive (Though I know you said you don't want to tie up that much money), so is there any chance of keeping both lenses?
If you are 100% certain you do not need the macro or the much smaller size of the 100L, then by all means, go for the 70-200L. I find I use my 100L 95% of the time as a portrait lens as well, but I would hate to give up the macro capabilities when I need it (Closeup of the rings, flowers, other wedding details, etc...). The 100L is also much more comfortable to hang around your neck for hours at a time when compared to the 70-200L, but that all depends on how you are using it I suppose.