If you have the money, get the MPE65... might not be the most suitable lens for nature macro though...
if you wanted a lens you carry around with you as you trek, and can shoot outdoors handheld, and money was no object, I'd say get the 180mm for the reach outdoors, not as good as the 100mm, so since money is no object, get that too. =P
Also, a good tripod and macro rail. you might not get to use it a lot outdoors, but its useful to have especially when money isn't an issue