What's the fastes SD Card that can be used before the speed advantage of the card is limited to the slow SD slot in the 5D, is it simply any 133x card?
https://www.sdcard.org/developers/overview/bus_speed/
It really doesn't matter, the fastest ones write at 10MB/sec in a 5D MK III unless low level formatted. A regular format does not erase old files, just marks them as ready to overwrite.
The higher speed specs are only for a new and fully erased card. This means that you would need to do a low level format perodically (depending on the card use). Otherwise, it will drop to 10mb/sec once it starts overwriting old files. If you get a very large one, you can do a low level format less often, be aware that low level formatting takes a very long time, you do not want to do a low level format for a large card in camera, it may run your battery down.