« Reply #4 on: September 22, 2012, 10:29:32 AM »
I have the same kit as you do. Daytime fill flash is supported by your E-TTL. I find my camera to meter E-TTL very hot - I frequently dial in -1/3 to -2/3 flash compensation. But fill flash is subject to taste - some like it very subtle and others like it more stark...
I agree with Revup67 - I think you are referring to 2nd curtain sync - where the shutter is open for a certain time and then the flash fires at the very end of the exposure? Also available with your gear...
Enjoy!

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5DIII, XSi, A2, 10s (x2), 20-35 2.8L, 28-70 2.8L, 70-200 2.8L, 40 2.8 Pancake, 50 2.5 Macro, 100 2.8 Macro, 135 2.0L, 135 2.8 Soft-Focus, Crappy EF-S Kit Lens, 430EX II, Metz 45 CL-4, Metz 60 CT-4 (x2), White Lightnings, and lots of other junk...