Personally I'd go for the Canon EF-S 16mm f/2 because it's better quality. Oh ... hang on ...
Mind you Canon aren't alone in this. Thom Hogan has repeatedly bashed Nikon on this point, suggesting that the quality and range of their DX cameras should be matched by better quality and range in their DX lenses.
Will be interesting to see how the Samyang 16mm compares with the Canon 10-22 at 16mm and the 17-55mm at 17mm. On a related note check this out:
http://www.photozone.de/canon-eos/831-canon_1855_3556stmis?start=2
The recent 18-55mm STM kit lens gets a solid review from Photozone (who are generally hard markers). Peak resolution is actually higher than for the 17-55mm, which is very surprising. Since I am considering the purchase of the latter lens it does cause me to wonder if it is really worth it at 4x the price...